Benzocycloalkanones in the Schmidt Reaction.
نویسندگان
چکیده
منابع مشابه
Gold(I)-catalyzed intramolecular acetylenic Schmidt reaction.
Substituted pyrroles were prepared by a gold(I)-catalyzed acetylenic Schmidt reaction of homopropargyl azides. The reaction allows for regiospecific substitution at each position of the pyrrole ring under mild conditions. A mechanism in which azides serve as nucleophiles toward gold(I)-activated alkynes with subsequent gold(I)-aided expulsion of dinitrogen is proposed.
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An intramolecular Schmidt reaction strategy for the synthesis of various derivatives of crispine A using azido-ketone as a key intermediate is described.
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Introduction We have all heard the old joke of school being all about the three “R’s”, Reading ‘Ritin and ‘Rithmatik, but because of increasing class sizes and reported lack of instruction time, writing has been passed over for the more “important” subjects. The advent of computers and the increasing ease of word processing have given teachers the ultimate excuse, but most beginning composition...
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چکیده ندارد.
15 صفحه اولOrganocatalytic diastereoselective synthesis of chiral decalines through the domino Claisen-Schmidt/Henry reaction.
General and operative domino Claisen-Schmidt/Henry (CS/H) reaction has been revealed to obtain highly substituted chiral decalines in good yields with excellent ees and des by using push-pull enamine catalysis.
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1964
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.18-0191